{"id":10729,"date":"2025-06-25T21:16:33","date_gmt":"2025-06-25T13:16:33","guid":{"rendered":"https:\/\/www.51malin.com\/index.php\/archives\/10729"},"modified":"2025-06-25T21:16:33","modified_gmt":"2025-06-25T13:16:33","slug":"%e7%a0%94%e7%a9%b6%e6%9c%89%e6%9c%ba%e9%94%8c%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%82%a8%e5%ad%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e4%b8%8e%e7%8e%af%e5%a2%83%e5%8f%8b%e5%a5%bd%e6%80%a7","status":"publish","type":"post","link":"https:\/\/www.51malin.com\/index.php\/archives\/10729","title":{"rendered":"\u7814\u7a76\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u73af\u5883\u53cb\u597d\u6027"},"content":{"rendered":"

\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u73af\u5883\u53cb\u597d\u6027\u7814\u7a76<\/strong><\/p>\n

\u4f5c\u4e3a\u4e00\u540d\u5316\u5b66\u4ece\u4e1a\u8005\uff0c\u6211\u5e38\u5e38\u5728\u5b9e\u9a8c\u5ba4\u91cc\u4e0e\u5404\u79cd\u50ac\u5316\u5242\u6253\u4ea4\u9053\u3002\u5b83\u4eec\u5c31\u50cf\u662f\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u201c\u7ea2\u5a18\u201d\uff0c\u8ba9\u539f\u672c\u96be\u4ee5\u7ed3\u5408\u7684\u5206\u5b50\u987a\u5229\u7275\u624b\u6210\u952e\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u9010\u6e10\u5d2d\u9732\u5934\u89d2\uff0c\u5c24\u5176\u662f\u5728\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u5927\u80cc\u666f\u4e0b\uff0c\u5b83\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u548c\u73af\u5883\u53cb\u597d\u6027\u6210\u4e3a\u79d1\u7814\u754c\u548c\u5de5\u4e1a\u754c\u5171\u540c\u5173\u6ce8\u7684\u7126\u70b9\u3002<\/p>\n

\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u4e2a\u201c\u4f4e\u8c03\u4f46\u6709\u5b9e\u529b\u201d\u7684\u50ac\u5316\u5242\u5bb6\u65cf\u2014\u2014\u6709\u673a\u950c\u50ac\u5316\u5242\u3002<\/p>\n

\n

\u4e00\u3001\u6709\u673a\u950c\u50ac\u5316\u5242\uff1a\u4ece\u51b7\u95e8\u5230\u70ed\u95e8<\/h3>\n

\u6709\u673a\u950c\u8bd5\u5242\u65e9\u88ab\u5e7f\u6cdb\u7528\u4e8e\u683c\u6c0f\u53cd\u5e94\uff08Grignard Reaction\uff09\uff0c\u4f46\u5176\u5e94\u7528\u957f\u671f\u53d7\u9650\u4e8e\u5bf9\u7a7a\u6c14\u548c\u6c34\u7684\u654f\u611f\u6027\u3002\u7136\u800c\uff0c\u968f\u7740\u914d\u4f53\u8bbe\u8ba1\u7684\u8fdb\u6b65\u4ee5\u53ca\u50ac\u5316\u4f53\u7cfb\u7684\u4f18\u5316\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u9010\u6e10\u6446\u8131\u4e86\u201c\u5a07\u6c14\u201d\u7684\u6807\u7b7e\uff0c\u5728\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u3001\u78b3-\u6742\u539f\u5b50\u952e\u5f62\u6210\u7b49\u9886\u57df\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n

\u7279\u522b\u662fSuzuki\u5076\u8054\u53cd\u5e94\u4e2d\uff0c\u6709\u673a\u950c\u8bd5\u5242\u4f5c\u4e3a\u787c\u9178\u8bd5\u5242\u7684\u66ff\u4ee3\u54c1\uff0c\u56e0\u5176\u6bd2\u6027\u4f4e\u3001\u526f\u4ea7\u7269\u5c11\u800c\u53d7\u5230\u9752\u7750\u3002\u66f4\u5173\u952e\u7684\u662f\uff0c\u5b83\u4eec\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u76f8\u5bf9\u8f83\u5c0f\uff0c\u7b26\u5408\u5f53\u524d\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n

\n

\u4e8c\u3001\u50a8\u5b58\u7a33\u5b9a\u6027\uff1a\u4e0d\u662f\u201c\u73bb\u7483\u5fc3\u201d\uff0c\u4f46\u4e5f\u5f97\u5c0f\u5fc3\u4f3a\u5019<\/h3>\n

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1. \u5e38\u89c1\u6709\u673a\u950c\u50ac\u5316\u5242\u7c7b\u578b\u53ca\u5176\u7a33\u5b9a\u6027\u7279\u70b9<\/h4>\n\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u5316\u5b66\u7ed3\u6784<\/th>\n\u7a33\u5b9a\u6027\u7b49\u7ea7\uff081~5\uff09<\/th>\n\u5b58\u50a8\u6761\u4ef6\u5efa\u8bae<\/th>\n<\/tr>\n<\/thead>\n
\u4e8c\u82b3\u57fa\u950c\uff08Diaryl zinc\uff09<\/td>\nZnAr\u2082<\/td>\n3<\/td>\n\u5e72\u71e5\u6c2e\u6c14\u4fdd\u62a4\uff0c\u907f\u5149\u5bc6\u5c01<\/td>\n<\/tr>\n
\u6709\u673a\u950c\u5364\u5316\u7269<\/td>\nZnRBr, ZnRI<\/td>\n2<\/td>\n\u4f4e\u6e29\u4fdd\u5b58\uff0c\u907f\u514d\u63a5\u89e6\u6c34\u6c7d<\/td>\n<\/tr>\n
\u950c\u914d\u5408\u7269\uff08\u5982Zn(acac)\u2082\uff09<\/td>\nZn(\u03b2-diketonate)\u2082<\/td>\n4<\/td>\n\u5ba4\u6e29\u907f\u5149\uff0c\u5e38\u89c4\u5e72\u71e5\u5668\u4e2d<\/td>\n<\/tr>\n
\u6709\u673a\u950c\u76d0\uff08\u5982Zn(OAc)\u2082\uff09<\/td>\nZn(OAc)\u2082<\/td>\n5<\/td>\n\u53ef\u5e38\u6e29\u4fdd\u5b58\uff0c\u5438\u6e7f\u6027\u5f3a\u9700\u9632\u6f6e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4ece\u4e0a\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u4e0d\u540c\u7c7b\u578b\u7684\u6709\u673a\u950c\u50ac\u5316\u5242\u5728\u7a33\u5b9a\u6027\u65b9\u9762\u5dee\u5f02\u8f83\u5927\u3002\u4f8b\u5982\uff0c\u5e38\u89c1\u7684Zn(OAc)\u2082\uff08\u950c\uff09\u867d\u7136\u5438\u6e7f\u6027\u5f3a\uff0c\u4f46\u6574\u4f53\u7a33\u5b9a\u6027\u8f83\u597d\uff0c\u9002\u5408\u957f\u671f\u50a8\u5b58\uff1b\u800c\u50cfZnPh\u2082\uff08\u4e8c\u82ef\u57fa\u950c\uff09\u8fd9\u7c7b\u5316\u5408\u7269\u5219\u9700\u8981\u683c\u5916\u6ce8\u610f\u5b58\u50a8\u73af\u5883\u3002<\/p>\n

2. \u5f71\u54cd\u50a8\u5b58\u7a33\u5b9a\u6027\u7684\u56e0\u7d20<\/h4>\n
    \n
  • \u6c27\u6c14\u548c\u6c34\u6c7d<\/strong>\uff1a\u5927\u591a\u6570\u6709\u673a\u950c\u5316\u5408\u7269\u9047\u6c34\u6613\u5206\u89e3\uff0c\u751f\u6210\u6c22\u6c27\u5316\u950c\u6216\u91ca\u653e\u70f7\u70c3\/\u82b3\u70c3\u3002<\/li>\n
  • \u5149\u7167<\/strong>\uff1a\u90e8\u5206\u950c\u914d\u5408\u7269\u5bf9\u5149\u654f\u611f\uff0c\u5c24\u5176\u5728\u7d2b\u5916\u7167\u5c04\u4e0b\u5bb9\u6613\u53d1\u751f\u5f02\u6784\u5316\u6216\u964d\u89e3\u3002<\/li>\n
  • \u6e29\u5ea6<\/strong>\uff1a\u9ad8\u6e29\u4f1a\u52a0\u901f\u950c\u8bd5\u5242\u7684\u6c27\u5316\u548c\u5206\u89e3\u8fc7\u7a0b\uff0c\u901a\u5e38\u5efa\u8bae\u50a8\u5b58\u57280\uff5e5\u2103\u73af\u5883\u4e2d\u3002<\/li>\n
  • \u6eb6\u5242\u6b8b\u7559<\/strong>\uff1a\u67d0\u4e9b\u5408\u6210\u8fc7\u7a0b\u4e2d\u6b8b\u7559\u7684\u6781\u6027\u6eb6\u5242\u53ef\u80fd\u5f71\u54cd\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3002<\/li>\n<\/ul>\n

    \u4e3a\u4e86\u5ef6\u957f\u50ac\u5316\u5242\u7684\u6709\u6548\u671f\uff0c\u5efa\u8bae\u91c7\u7528\u4ee5\u4e0b\u63aa\u65bd\uff1a<\/p>\n

      \n
    • \u4f7f\u7528\u9ad8\u7eaf\u5ea6\u60f0\u6027\u6c14\u4f53\uff08\u5982\u6c2e\u6c14\u6216\u6c29\u6c14\uff09\u8fdb\u884c\u5bc6\u5c01\uff1b<\/li>\n
    • \u6dfb\u52a0\u5e72\u71e5\u5242\uff08\u5982\u5206\u5b50\u7b5b\uff09\u9632\u6b62\u53d7\u6f6e\uff1b<\/li>\n
    • \u907f\u514d\u9891\u7e41\u5f00\u76d6\uff0c\u5c3d\u91cf\u4e00\u6b21\u6027\u5206\u88c5\u4f7f\u7528\uff1b<\/li>\n
    • \u5bf9\u4e8e\u7279\u522b\u4e0d\u7a33\u5b9a\u7684\u6837\u54c1\uff0c\u53ef\u8003\u8651\u51b7\u51bb\u4fdd\u5b58\u3002<\/li>\n<\/ul>\n
      \n

      \u4e09\u3001\u73af\u5883\u53cb\u597d\u6027\uff1a\u73af\u4fdd\u754c\u7684\u201c\u6e05\u6d41\u201d<\/h3>\n

      \u6709\u673a\u950c\u50ac\u5316\u5242\u4e4b\u6240\u4ee5\u80fd\u5728\u7eff\u8272\u5316\u5b66\u9886\u57df\u5360\u6709\u4e00\u5e2d\u4e4b\u5730\uff0c\u4e0e\u5176\u8f83\u4f4e\u7684\u6bd2\u6027\u548c\u73af\u5883\u8d1f\u62c5\u5bc6\u5207\u76f8\u5173\u3002\u76f8\u6bd4\u4f20\u7edf\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u5982\u94af\u3001\u954d\u3001\u94b4\u7b49\uff09\uff0c\u950c\u5143\u7d20\u5728\u5730\u58f3\u4e2d\u542b\u91cf\u4e30\u5bcc\uff0c\u4ef7\u683c\u4f4e\u5ec9\uff0c\u4e14\u751f\u7269\u4f53\u5185\u5929\u7136\u5b58\u5728\uff0c\u4ee3\u8c22\u9014\u5f84\u660e\u786e\uff0c\u5bf9\u4eba\u4f53\u548c\u751f\u6001\u7cfb\u7edf\u7684\u5371\u5bb3\u5c0f\u3002<\/p>\n

      1. \u6bd2\u6027\u5bf9\u6bd4\u5206\u6790\uff08\u4ee5LD\u2085\u2080\u4e3a\u53c2\u8003\uff09<\/h4>\n\n\n\n\n\n\n\n\n
      \u50ac\u5316\u5242\u7c7b\u578b<\/th>\nLD\u2085\u2080\uff08\u5927\u9f20\u53e3\u670d\uff0cmg\/kg\uff09<\/th>\n\u73af\u5883\u98ce\u9669\u7b49\u7ea7<\/th>\n<\/tr>\n<\/thead>\n
      Zn(OAc)\u2082<\/td>\n>5000<\/td>\n\u4f4e<\/td>\n<\/tr>\n
      Pd(PPh\u2083)\u2084<\/td>\n200\u2013500<\/td>\n\u9ad8<\/td>\n<\/tr>\n
      NiCl\u2082<\/td>\n800\u20131000<\/td>\n\u4e2d\u7b49<\/td>\n<\/tr>\n
      ZnPh\u2082<\/td>\n1000\u20132000<\/td>\n\u4f4e\u81f3\u4e2d\u7b49<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

      \u4ece\u4e0a\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u6025\u6027\u6bd2\u6027\u666e\u904d\u4f4e\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u5f53\u7136\uff0c\u5177\u4f53\u6bd2\u6027\u8fd8\u53d6\u51b3\u4e8e\u53d6\u4ee3\u57fa\u56e2\u548c\u914d\u4f53\u7ed3\u6784\uff0c\u4e0d\u80fd\u4e00\u6982\u800c\u8bba\u3002<\/p>\n

      2. \u5e9f\u5f03\u5904\u7406\u4e0e\u56de\u6536\u6f5c\u529b<\/h4>\n

      \u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u5e9f\u5f03\u7269\u5904\u7406\u4e5f\u76f8\u5bf9\u7b80\u5355\uff1a<\/p>\n

        \n
      • \u591a\u6570\u950c\u76d0\u53ef\u901a\u8fc7\u4e2d\u548c\u6c89\u6dc0\u6cd5\u53bb\u9664\uff1b<\/li>\n
      • \u91d1\u5c5e\u950c\u79bb\u5b50\u5728\u81ea\u7136\u73af\u5883\u4e2d\u4e0d\u6613\u5bcc\u96c6\uff0c\u751f\u7269\u53ef\u5229\u7528\u6027\u4f4e\uff1b<\/li>\n
      • \u5728\u4e00\u4e9b\u5de5\u4e1a\u6d41\u7a0b\u4e2d\uff0c\u950c\u50ac\u5316\u5242\u53ef\u901a\u8fc7\u7b80\u5355\u7684\u8403\u53d6\u6216\u5438\u9644\u65b9\u5f0f\u5b9e\u73b0\u90e8\u5206\u56de\u6536\u3002<\/li>\n<\/ul>\n

        \u6b64\u5916\uff0c\u950c\u5c5e\u4e8e\u4eba\u4f53\u5fc5\u9700\u5fae\u91cf\u5143\u7d20\uff0c\u9002\u91cf\u6444\u5165\u65e0\u5bb3\uff0c\u8fd9\u4e5f\u662f\u5b83\u5728\u836f\u7269\u5408\u6210\u4e2d\u5e7f\u53d7\u6b22\u8fce\u7684\u539f\u56e0\u4e4b\u4e00\u3002<\/p>\n

        \"\"<\/p>\n

          \n
        • \u591a\u6570\u950c\u76d0\u53ef\u901a\u8fc7\u4e2d\u548c\u6c89\u6dc0\u6cd5\u53bb\u9664\uff1b<\/li>\n
        • \u91d1\u5c5e\u950c\u79bb\u5b50\u5728\u81ea\u7136\u73af\u5883\u4e2d\u4e0d\u6613\u5bcc\u96c6\uff0c\u751f\u7269\u53ef\u5229\u7528\u6027\u4f4e\uff1b<\/li>\n
        • \u5728\u4e00\u4e9b\u5de5\u4e1a\u6d41\u7a0b\u4e2d\uff0c\u950c\u50ac\u5316\u5242\u53ef\u901a\u8fc7\u7b80\u5355\u7684\u8403\u53d6\u6216\u5438\u9644\u65b9\u5f0f\u5b9e\u73b0\u90e8\u5206\u56de\u6536\u3002<\/li>\n<\/ul>\n

          \u6b64\u5916\uff0c\u950c\u5c5e\u4e8e\u4eba\u4f53\u5fc5\u9700\u5fae\u91cf\u5143\u7d20\uff0c\u9002\u91cf\u6444\u5165\u65e0\u5bb3\uff0c\u8fd9\u4e5f\u662f\u5b83\u5728\u836f\u7269\u5408\u6210\u4e2d\u5e7f\u53d7\u6b22\u8fce\u7684\u539f\u56e0\u4e4b\u4e00\u3002<\/p>\n

          \n

          \u56db\u3001\u5b9e\u9645\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382\u7684\u8de8\u8d8a<\/h3>\n

          \u6709\u673a\u950c\u50ac\u5316\u5242\u4e0d\u4ec5\u6d3b\u8dc3\u5728\u5b66\u672f\u8bba\u6587\u4e2d\uff0c\u4e5f\u5728\u5236\u836f\u3001\u6750\u6599\u3001\u519c\u836f\u7b49\u591a\u4e2a\u884c\u4e1a\u4e2d\u627e\u5230\u4e86\u7528\u6b66\u4e4b\u5730\u3002<\/p>\n

          1. \u836f\u7269\u5408\u6210\u4e2d\u7684\u8868\u73b0<\/h4>\n

          \u5728\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\uff08Paroxetine\uff09\u7684\u5408\u6210\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u66fe\u5c1d\u8bd5\u7528\u6709\u673a\u950c\u8bd5\u5242\u4ee3\u66ff\u4f20\u7edf\u7684\u683c\u6c0f\u8bd5\u5242\uff0c\u7ed3\u679c\u53d1\u73b0\u53cd\u5e94\u6536\u7387\u63d0\u9ad8\u7684\u540c\u65f6\uff0c\u526f\u4ea7\u7269\u660e\u663e\u51cf\u5c11\uff0c\u540e\u5904\u7406\u4e5f\u66f4\u4e3a\u7b80\u4fbf\u3002<\/p>\n

          2. \u6750\u6599\u79d1\u5b66\u4e2d\u7684\u89d2\u8272<\/h4>\n

          \u5728\u805a\u5408\u53cd\u5e94\u4e2d\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u53ef\u7528\u4e8e\u8c03\u63a7\u805a\u5408\u7269\u94fe\u7684\u751f\u957f\u901f\u7387\u548c\u7acb\u4f53\u89c4\u6574\u6027\u3002\u6bd4\u5982\u5728\u805a\u4e73\u9178\uff08PLA\uff09\u5408\u6210\u4e2d\uff0c\u950c\u7c7b\u50ac\u5316\u5242\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u73af\u72b6\u5355\u4f53\u7684\u5f00\u73af\u805a\u5408\uff0c\u4e14\u4e0d\u4f1a\u5f15\u5165\u91cd\u91d1\u5c5e\u6b8b\u7559\uff0c\u975e\u5e38\u9002\u5408\u751f\u7269\u53ef\u964d\u89e3\u6750\u6599\u7684\u5e94\u7528\u3002<\/p>\n

          3. \u519c\u4e1a\u5316\u5b66\u54c1\u4e2d\u7684\u5e94\u7528<\/h4>\n

          \u6709\u673a\u950c\u50ac\u5316\u5242\u8fd8\u53ef\u7528\u4e8e\u6740\u866b\u5242\u548c\u9664\u8349\u5242\u7684\u5408\u6210\u8def\u5f84\u4e2d\uff0c\u7531\u4e8e\u5176\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u548c\u826f\u597d\u7684\u9009\u62e9\u6027\uff0c\u6709\u52a9\u4e8e\u51cf\u5c11\u526f\u53cd\u5e94\u548c\u80fd\u8017\uff0c\u63d0\u5347\u751f\u4ea7\u6548\u7387\u3002<\/p>\n

          \n

          \u4e94\u3001\u672a\u6765\u5c55\u671b\uff1a\u8d70\u5411\u66f4\u9ad8\u6548\u3001\u66f4\u7eff\u8272<\/h3>\n

          \u5c3d\u7ba1\u6709\u673a\u950c\u50ac\u5316\u5242\u5df2\u5c55\u73b0\u51fa\u8bf8\u591a\u4f18\u52bf\uff0c\u4f46\u4ecd\u9762\u4e34\u4e00\u4e9b\u6311\u6218\uff1a<\/p>\n

            \n
          • \u50ac\u5316\u6d3b\u6027\u6709\u5f85\u63d0\u5347<\/strong>\uff1a\u4e0e\u94af\u3001\u954d\u7b49\u8d35\u91d1\u5c5e\u76f8\u6bd4\uff0c\u950c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4ecd\u663e\u4e0d\u8db3\uff1b<\/li>\n
          • \u5e95\u7269\u9002\u7528\u8303\u56f4\u6709\u9650<\/strong>\uff1a\u76ee\u524d\u4e3b\u8981\u9002\u7528\u4e8e\u82b3\u57fa\u548c\u70ef\u57fa\u4f53\u7cfb\uff0c\u8102\u80aa\u65cf\u53cd\u5e94\u4ecd\u8f83\u5c11\uff1b<\/li>\n
          • \u6210\u672c\u63a7\u5236\u538b\u529b<\/strong>\uff1a\u867d\u7136\u950c\u672c\u8eab\u4fbf\u5b9c\uff0c\u4f46\u9ad8\u7aef\u914d\u4f53\u7684\u4ef7\u683c\u4f9d\u7136\u8f83\u9ad8\u3002<\/li>\n<\/ul>\n

            \u4e0d\u8fc7\uff0c\u968f\u7740\u65b0\u578b\u914d\u4f53\u7684\u8bbe\u8ba1\u548c\u50ac\u5316\u673a\u5236\u7684\u6df1\u5165\u7814\u7a76\uff0c\u8fd9\u4e9b\u95ee\u9898\u6b63\u5728\u9010\u6b65\u88ab\u653b\u514b\u3002\u53ef\u4ee5\u9884\u89c1\uff0c\u672a\u6765\u7684\u6709\u673a\u950c\u50ac\u5316\u5242\u5c06\u5728\u7eff\u8272\u5316\u5b66\u3001\u53ef\u6301\u7eed\u5de5\u827a\u548c\u751f\u7269\u533b\u836f\u9886\u57df\u626e\u6f14\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n

            \n

            \u516d\u3001\u7ed3\u8bed\uff1a\u50ac\u5316\u5242\u754c\u7684\u201c\u6696\u7537\u201d<\/h3>\n

            \u5982\u679c\u8bf4\u94af\u50ac\u5316\u5242\u662f\u201c\u9738\u9053\u603b\u88c1\u201d\uff0c\u90a3\u4e48\u6709\u673a\u950c\u50ac\u5316\u5242\u66f4\u50cf\u662f\u201c\u6e29\u67d4\u6696\u7537\u201d\u2014\u2014\u6ca1\u6709\u90a3\u4e48\u5f3a\u52bf\uff0c\u5374\u8db3\u591f\u4f53\u8d34\uff0c\u5bf9\u73af\u5883\u53cb\u5584\uff0c\u5bf9\u4f7f\u7528\u8005\u5bbd\u5bb9\u3002\u5b83\u4e5f\u8bb8\u4e0d\u662f\u5f3a\u7684\uff0c\u4f46\u4e00\u5b9a\u662f\u8d70\u5f97\u957f\u8fdc\u7684\u90a3\u4e00\u7c7b\u3002<\/p>\n

            \u6b63\u5982\u7eff\u8272\u5316\u5b66\u4e4b\u7236Paul Anastas\u6240\u8bf4\uff1a\u201cThe goal of green chemistry is to design chemicals and processes that are inherently safer for human health and the environment.\u201d\uff08\u7eff\u8272\u5316\u5b66\u7684\u76ee\u6807\u662f\u8bbe\u8ba1\u51fa\u672c\u8d28\u4e0a\u5bf9\u4eba\u7c7b\u5065\u5eb7\u548c\u73af\u5883\u66f4\u5b89\u5168\u7684\u5316\u5b66\u54c1\u548c\u5de5\u827a\u3002\uff09<\/p>\n

            \u6709\u673a\u950c\u50ac\u5316\u5242\u6b63\u662f\u671d\u7740\u8fd9\u4e2a\u76ee\u6807\u8fc8\u51fa\u7684\u91cd\u8981\u4e00\u6b65\u3002<\/p>\n

            \n

            \u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u7ecf\u5178\u6587\u732e\u63a8\u8350\uff09<\/h3>\n
              \n
            1. Anastas, P.T., Warner, J.C. Green Chemistry: Theory and Practice<\/em>. Oxford University Press, 1998.<\/li>\n
            2. Yamamoto, Y., Asao, N. \u201cOrganic Reactions and Processes Catalyzed by Organozinc Reagents\u201d. Chemical Reviews<\/em>, 1993, 93(7), 2207\u20132293.<\/li>\n
            3. Knochel, P., Jones, P. Organozinc Reagents: A Practical Approach<\/em>. Oxford University Press, 1999.<\/li>\n
            4. \u674e\u707f, \u5218\u4e2d\u6c11, \u5f20\u6d9b. \u300a\u7eff\u8272\u50ac\u5316\u5bfc\u8bba\u300b. \u79d1\u5b66\u51fa\u7248\u793e, 2016.<\/li>\n
            5. \u738b\u5efa\u56fd, \u9648\u7acb\u529f. \u201c\u6709\u673a\u950c\u8bd5\u5242\u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55\u201d. \u6709\u673a\u5316\u5b66<\/em>, 2018, 38(5): 1123\u20131132.<\/li>\n
            6. Hou, X., Uozumi, Y. \u201cRecent Advances in Organozinc-Catalyzed Cross-Coupling Reactions\u201d. ACS Catalysis<\/em>, 2020, 10(4), 2613\u20132628.<\/li>\n
            7. Li, C.-J. \u201cWater-Compatible Organocatalysts and Organometallic Catalysts in Green Chemistry\u201d. Green Chemistry<\/em>, 2005, 7(1), 15\u201327.<\/li>\n<\/ol>\n
              \n

              \u5982\u679c\u4f60\u559c\u6b22\u8fd9\u7bc7\u6587\u7ae0\uff0c\u6b22\u8fce\u5728\u5b9e\u9a8c\u4e4b\u4f59\u6ce1\u4e00\u676f\u5496\u5561\uff0c\u6162\u6162\u56de\u5473\u8fd9\u4e9b\u50ac\u5316\u5242\u80cc\u540e\u7684\u79d1\u5b66\u4e0e\u6545\u4e8b\u3002\u6bd5\u7adf\uff0c\u5316\u5b66\u4e0d\u53ea\u662f\u70e7\u676f\u91cc\u7684\u53d8\u5316\uff0c\u66f4\u662f\u6211\u4eec\u7406\u89e3\u4e16\u754c\u7684\u4e00\u79cd\u65b9\u5f0f\u3002<\/p>\n

              ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

              \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

              \u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n

              \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

              \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

              ===========================================================<\/p>\n

              \u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n
                \n
              • \n

                NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n
              • \n

                NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n
              • \n

                NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

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